Tag Archive: Atoms Molecules Stochiometry

Concentrations of Solutions in Atoms, Molecules & Stoichiometry

In the earlier post, i mentioned that this topic Atoms, Molecules & Stoichiometry is usually taught revised  in the 1st few weeks in Junior Colleges and Centralised Institute. In fact, the college teachers and lecturers do not really teach you but gives you questions to attempt – as a form of revision on a topic called Mole Calculations / Mole Concepts that  you have learned in GCE O-Level Chemistry or other Basic Chemistry course (Click HERE if you need a quick revision).

One of the most common type of questions are related to Concentrations of Solutions.

Always remember that a Solution is made of of Solute (the minor component and usually a solid) and Solvent (the major component and usually a liquid, with water being most common).

I.e. Solution = Solute + Solvent

E.g. Salt Solution = NaCl (Solute) + Water (Solvent)

We can make the Salt Solution more diluted by either adding more water to it or removing solute from it.

The opposite must be true. To make the Salt Solution more concentrated, we can either remove the water or add more solute to it.

Example:

a) What is the Concentration of the salt solution when 117g of NaCl is added into 500 cm3 of water?

b) What is the corresponding Molar Concentration in mol/dm3?

Suggested Answer:

Using the formulae related to Concentration of Solutions that we discussed previously;

a) Concentration of Salt Solution = Mass of NaCl (g) / Volume of Solution (dm3)

= 117 g / 0.5 dm3

= 234 g/dm3

b) Mole of NaCl = Mass of NaCl (g) / Mr of NaCl

= 117 g / 58.5

= 2 mol

Molar Concentration = Mole of NaCl (mol) / Volume of Solution (dm3)

= 2 mol / 0.5 dm3

= 4.00 mol / dm3

Hope you are learning something useful on the above example. I would love to hear from you.

I always believed you learn something by doing it, and not reading it. As such, here is an quick check question for you to try it out.

Quick Check 1:

How many moles of sodium ions, Na+, are present in 250 cm3 of 0.4 mol/dm3 of Sodium Sulfate, Na2SO4?

PS: Try out the question and leave your answers in the comment section below.

Key Definitions & Formulae in Atoms, Molecules and Stoichiometry

Most Junior Colleges and Centralised Institute will start their GCE A-Level Chemistry curriculum with Physical Chemistry, and the most common topic will be Atoms, Molecules and Stoichiometry.

(Photo courtesy Rocker Dude)

This is essentially a re-cap of what the students have learned during their GCE O-Level Chemistry studies and they include sub-topics such as:

  • Relative masses of Atoms & Molecules
  • Definition of Mole in terms of Avogadro Constant
  • Relative Atomic Mass based on Relative Abundances of its Isotopes
  • Calculation of Empirical & Molecular Formulae
  • Calculations using Mole Concepts involving Reacting Masses, Volume of Gases and Concentrations of Solutions

However, the questions given in their tutorials and tests are usually pitched at a more challenging level and i realised that many Junior College (JC) students are not able to score well in it. My current group of JC A-Level Chemistry students can attest to it.

The only new Chemistry Concepts they learned here is a Mathematical Formulae to “Calculate the Molecular Formulae of Hydrocarbons using Combustion Data“. We will talk about this later in more details. Stay tuned!

Meanwhile, i would like to revise with you some

Key Definitions that you are expected to know:

* Mole

- is the unit of the amount of substance containing a number of particles equal to Avogadro constant

* Avogadro Constant

- states that there are 6.02 x 1023 particles in one mole of substance

* Empirical Formula

- Simplest formula which shows the ratio of the atoms of the different elements in a compound

* Molecular Formula

- Formula which shows the actual number of atoms of each element present in one molecule of a compound

* Excess Reagent

- Reactants that are in excess amount and are not consumed at the end of the chemical reaction

* Limiting Reagent

- Reactants that are completely consumed at the end of the reaction and determines the amount of product (s) formed

* Theoretical Yield

- Maximum amount of  a product that can be obtained in a reaction from the given amount of reactants

* Actual Yield

- Actual amount of product obtained from the reaction and usually lesser due to incomplete reaction or product loss during reaction

* Molar Volume

- Volume occupied by 1 mole of Gas, which is 22.4 dm3 (at s.t.p) and 24.0 dm3 (at r.t.p)

Key Formulae you need to know are summarised below:

No. of Moles = Mass of Substance (g) / Molar Mass of Substance

No. of Moles of Gas = Volume of Gas / Molar Volume

Relative Atomic Mass = Σ (Isotopic Mass x Percentage Abundance) / 100

% Yield = (Actual Amount) / (Theoretical Amount ) x 100%

Concentration (g/dm3) = Mass of Solute (g) / Volume of Solution (dm3)

Molar Concentration (mol/dm3) = Moles of Solute (mol) / Volume of Solution (dm3)

In the next few posts, we will look at a large number of worked examples, particularly on Mole and Chemical Calculations. I will also give you some Quick Check Questions consisting of examination-type questions to practice what you learn. Stay Tuned!

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